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Under physiological conditions, GSH quenches oxidizing substances (such as reactive hydroxyl free radicals, peroxynitrite, and H 2 O 2 ) directly or reduces hydrogen peroxide (or lipid peroxide (lipid-OOH)) to water (or the corresponding lipid alcohol (lipid-OH)) under the catalysis of GPX (summarized in Fig

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After taking a closer look at the chemical structures of both compounds, the difference in the interaction should be caused either by the different aromatic substitution at the D‐Trp end (L‐His vs